In Tokyo, there is the Tokyo Tower. 東京に東京タワーにあります。
And direction:
I'm going to the store tomorrow. 明日店に行きます。
Sakuratree
There are a few places where に can't be used. ×友だちにのプレゼント [tomodachi ni no purezento] BAD ○友だちへのプレゼント [tomodachi he no purezento] GOOD
And some where only に can be used 事務所にパソコンがある [jimusho ni pasokon ga aru]
Amatuka
In the Notes section, the first sample talks about three hours, the time span, not three o'clock, 三時間 is not 三時 And the second means It's in Tokyo *at the Tokyo Tower. I think.